Supposedly, only human-hair wigs are meant to be heat-styled, at risk of melting, frizzing or nuking. I found this to be true of cheaper costume wigs, and many normal "high-quality" European wigs.
However, every single wig we've experimented on containing Toyokalon (and comparable Japanese fibers) has held up and taken heat-straightening restyling without any damage to the strands. In order to get the results, I use a regular human-hair ceramic flat iron on setting 1 and clamp down briefly, repeatedly overlapping the heated areas.
| This black wig came with the long back strands perfectly straight already, but for some reason, the mid-length sections were curled inward originally. The editing is shown in the right of the picture.
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| Here's a more extreme example. The side bangs here were originally as tightly curled as the back of the wig.
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| This is the wig I mutilated for Riku. (The original state is shown below.) Amongst other adjustments, straightening out the waves worked out well, and I still had a thick wig with good lift to spike the right way.
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